SciELO - Scientific Electronic Library Online

 
vol.25 issue3A New Formulation of the Frequency Factor in the Expression for the Rate Constant of Interfacial Charge TransfersCyclic Voltammetric Investigation on the Catalysis of Electrodeposited Manganese Oxide on the Electrochemical Reduction of Oxygen (ORR) in Room Temperature Ionic Liquids (RTILs) of 1-Ethyl-3-Methylimidazolium Tetrafluorobroate (EMIBF4) on Glass Carbon (GC) Electrode author indexsubject indexarticles search
Home Pagealphabetic serial listing  

Services on Demand

Journal

Article

Indicators

Related links

  • Have no similar articlesSimilars in SciELO

Share


Portugaliae Electrochimica Acta

Print version ISSN 0872-1904

Port. Electrochim. Acta vol.25 no.3 Coimbra  2007

 

Oil Soluble Corrosion Inhibitor on Microbiologically Influenced Corrosion in Diesel Transporting Pipeline

N. Muthukumar, S. Maruthamuthu, S. Mohanan, N. Palaniswamy*

 

Corrosion Protection Division, Central Electrochemical Research Institute, Karaikudi – 630 006, India

Received 3 August 2006; accepted 8 November 2006

 

 

Abstract

The effect of oil soluble commercial corrosion inhibitors (OSCI) on the growth of bacteria and its corrosion inhibition efficiency were investigated. Corrosion inhibition efficiency was studied by rotating cage test and the nature of biodegradation of corrosion inhibitor was also analyzed by using FTIR, NMR and GC-MS. This isolate has the capacity to degrade the aromatic and aliphatic hydrocarbon present in the corrosion inhibitors. The degraded products of corrosion inhibitors and bacterial activity determine the electrochemical behaviour of API 5LX steel. The influence of bacterial activity on degradation of corrosion inhibitor and its influence on corrosion of API 5LX have been evaluated by employing weight loss techniques and electrochemical studies. The present study also emphasizes the importance of evaluation of oil soluble corrosion inhibitor in stagnant model (flow loop test) and discusses the demerits of the oil soluble corrosion inhibitors in petroleum product pipeline.

 

Keywords: diesel pipeline, corrosion inhibitors, rotating cage method, flow loop method, biodegradation, microbiologically influenced corrosion.

 

Texto disponível em PDF

Full text only in PDF format

 

 

References

1. D.H. Pope et al., Mitigation strategies for microbiologically influenced corrosion in gas industry facilities, CORROSION/89, paper no.192 (Houston, TX: NACE,1989).

2. L.H. Lin et.al., Org. Geochem. 4,5 (1989) 511-523.

3. H. Kobayashi, B.E. Rittman, Environmen. Sci. Technol. 16, 3 (1982) 170-183.

4. A. Rajasekar, S. Maruthamuthu, N. Palaniswamy, A. Rajendran, Biodegradation of corrosion inhibitors and their influence on petroleum product pipeline, Microbiological Research (2006) (in press).

5. F.M. Bento and C.C. Gaylarde, Biodeterioration of stored diesel oil: studies in Brazil, Int. Biodeterior. Biodeg. 47 (2001) 107-112.        [ Links ]

6. J. L. Shennan, (1988) Control of microbial contamination of fuels in storage. 248–254. In D.R. Houghton, R.N. Smith, and H.O.W. Eggins (ed.), Biodeterioration, Elsevier, Barking.

7. H.A. Videla and W.G. Characklis, Biofouling and microbially influenced corrosion, Int. Biodeterior. Biodeg. 29 (1992) 195-212.

8. D.A. Jones and P.S. Amy, A thermodynamic interpretation of microbiologically influenced corrosion, Corrosion. 58 (2002) 638–645.

9. B. Little and R. Ray, A perspective on corrosion inhibition by biofilms, Corrosion. 58 (2002) 424–428.

10. H.A. Videla, S.G.G. Saraiva, P.S. Guiamet, Microbial degradation of film-forming inhibitors and its possible effects on corrosion inhibition performance, corrosion/2000, paper no.00386 (Houston, TX, NACE International, 2000).

11. P. Poupin, N. Truffaut, B. Combourieu, B. Besse, P. Sancelme, M.H. Veschambre, A.M. Delort, Applied and Environmental Microbiology 64, 1 (1998) 159.

12. F. Bento, I.B. Beech, C.C. Gaylarde, G.E. Englert and I.L. Muller, Degradation and corrosive activities of fungi in a diesel–mild steel–aqueous system, World Journal of Microbiology  Biotechnology  21 (2005) 135–142.

13. N. Muthukumar, S. Mohanan,  S. Maruthamuthu, P. Subramanian, N. Palaniswamy, M. Raghavan, Role of Brucella sp. and Gallionella sp. in oil degradation and corrosion, Electrochem. Comm. 5 (2003) 421-427.

14. R. Dominguez, J.R.G.G. Caloca, J.M. Flores, E.M.I. Nunez, "Study on the Presence of Pseudomonas fluorescens on the Efficacy of Three Corrosion Inhibitors," (in Spanish), 3rd NACE Latin American Region Corrosion Congress, Cancun, Q.Roo, Mexico, Book of  abstracts, 51-52, 1998.

15. S. Maruthamuthu, S. Mohanan, A. Rajasekar, N. Muthukumar, P. Ponmarippan, P. Subramanian, N. Palaniswamy, Role of corrosion inhibitor on bacterial corrosion in petroleum product pipelines, Ind. J. Chem. Tech (In press).

16. S. Papavinasam, R.W. Review, M. Attard, A. Demoz, H. Sun, J.C. Donini, K.H. Michaelian, Laboratory methodologies for corrosion inhibitor selection, Material Performance 39 (8) (2000) 58.

17. E.R. Schiapparelli, B.R. Meybaum, Microbial contamination and corrosion of aircraft integral fuel storage tanks – Evaluation and risk control,  Material Performance 19 (10) (1980)  47.

18. E.R. Freiter, Effect of a corrosion inhibitor on bacteria and microbiologically influenced corrosion, Corrosion 48, 4  (1992) 266-276.

19. R. Prasad, Selection of Corrosion Inhibitors to Control Microbiologically Influenced Corrosion, CORROSION/98, paper no. 276, (Houston, TX: NACE International, 1998).

20. H.A. Videla, S.G.G. Saravia, P.S. Guiamet, Microbial degradation of film-forming inhibitors and its possible effects on Corrosion inhibition performance, corrosion/2000, paper no.00386 (Houston, TX, NACE International, 2000).

 

 

*Corresponding author. E-mail address: swamy23@rediffmail.com

Creative Commons License All the contents of this journal, except where otherwise noted, is licensed under a Creative Commons Attribution License